methyl 4-isocyanatobenzoate

Names

[ Name ]:
methyl 4-isocyanatobenzoate

[Synonym ]:
MFCD01863690
4-carbomethoxyphenyl isocyanate
4-isocyanatobenzoic acid methyl ester
4-Isocyanato-benzoesaeure-methylester
4-methoxycarbonylphenyl isocyanate

Chemical & Physical Properties

[ Density]:
1.15g/cm3

[ Boiling Point ]:
264.9ºC at 760mmHg

[ Melting Point ]:
50-52ºC(lit.)

[ Molecular Formula ]:
C₉H₇NO₃

[ Molecular Weight ]:
177.15700

[ Flash Point ]:
123.2ºC

[ Exact Mass ]:
177.04300

[ PSA ]:
55.73000

[ LogP ]:
1.44050

[ Vapour Pressure ]:
0.00943mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H334-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P342 + P311

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
22-26-36

[ RIDADR ]:
UN 3335

[ HS Code ]:
2929109000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2929109000

[ Summary ]:
2929109000. other isocyanates. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis and antitumor activity of heterocycles related to carbendazim. Remers WA, et al.

J. Heterocycl. Chem. 52(1) , 136-141, (2015)