t-Butyl 2-bromo isobutyrate

Names

[ Name ]:
t-Butyl 2-bromo isobutyrate

[Synonym ]:
2-Bromoisobutyric Acid tert-Butyl Ester
t-Butyl 2-bromo isobutyrate
tert-butyl 2-bromo-2-methyl-propionate
2-bromo-2-methylpropanoic acid tert-butyl ester
MFCD00051908
tert-Butyl 2-bromoisobutyrate
tert-Butyl 2-bromo-2-methylpropionate
tert-Butyl-2-brom-2-methylpropanoat
tert-butyl 2-bromo-2-methylpropanoate
EINECS 245-924-7
Propanoic acid, 2-bromo-2-methyl-, 1,1-dimethylethyl ester
2-Methyl-2-propanyl 2-bromo-2-methylpropanoate
2-Bromoisobutyric acid tert-butylester
2-bromo-2-methyl-propionic acid tert-butyl ester
tert-Butyl α-bromoisobutyrate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
175.5±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₅BrO₂

[ Molecular Weight ]:
223.107

[ Flash Point ]:
66.8±11.9 °C

[ Exact Mass ]:
222.025528

[ PSA ]:
26.30000

[ LogP ]:
2.76

[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.460

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
3334

[ WGK Germany ]:
2

[ Hazard Class ]:
9

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Controlled synthesis of homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate via RAFT radical polymerisation.

Chem. Commun. (Camb.) (4) , 538-9, (2003)

Reversible addition-fragmentation chain transfer (RAFT) radical polymerisation enables to synthesise well-defined homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate, which a...