2-Bromo-1H-isoindole-1,3(2H)-dione

Names

[ Name ]:
2-Bromo-1H-isoindole-1,3(2H)-dione

[Synonym ]:
N-Bromophthalimide
N-bromoisoindole-1,3-dione
2-Bromoisoindoline-1,3-dione
EINECS 219-467-9
MFCD00005888
1H-Isoindole-1,3(2H)-dione, 2-bromo-
2-Bromo-1H-isoindole-1,3(2H)-dione

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
332.3±25.0 °C at 760 mmHg

[ Melting Point ]:
194-198 °C(lit.)

[ Molecular Formula ]:
C₈H₄BrNO₂

[ Molecular Weight ]:
226.027

[ Flash Point ]:
154.8±23.2 °C

[ Exact Mass ]:
224.942535

[ PSA ]:
37.38000

[ LogP ]:
1.72

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.705

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2925190090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2925190090

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Enantioselective synthesis of multisubstituted biaryl skeleton by chiral phosphoric acid catalyzed desymmetrization/kinetic resolution sequence.

J. Am. Chem. Soc. 135(10) , 3964-70, (2013)

Described herein is the enantioselective synthesis of multisubstituted biaryl derivatives by chiral phosphoric acid catalyzed asymmetric bromination. Two asymmetric reactions (desymmetrization and kin...

Titrimetric determination of acetylenic hyponotics using organic brominating agents.

Pharm. Weekbl. Sci. 10(2) , 90-2, (1988)

A titrimetric method is described for the determination of three acetylenic hypnotics, namely ethchlorvynol, ethinamate, and methylpentynol carbamate, in bulk and in dosage forms. The method involves ...

N-bromoimide/DBU combination as a new strategy for intermolecular allylic amination.

Org. Lett. 15(20) , 5186-9, (2013)

Allylic amination reactions of alkenes, with an NBP (N-bromophthalimide) or NBS (N-bromosuccinimide)/DBU combination, were developed, in which both internal and external nitrogen nucleophiles can be i...