dichlorotriphenylphosphorane
Names
[ CAS No. ]:
2526-64-9
[ Name ]:
dichlorotriphenylphosphorane
[Synonym ]:
MFCD00010359
Dichlorotriphenylphosphorane
triphenylphosphine dichloride
triphenyldichlorophosphorane
triphenylphosphine chloride
Chemical & Physical Properties
[ Melting Point ]:
85ºC
[ Molecular Formula ]:
C18H15Cl2P
[ Molecular Weight ]:
333.19100
[ Flash Point ]:
68 °F
[ Exact Mass ]:
332.02900
[ PSA ]:
13.59000
[ LogP ]:
4.82380
[ Water Solubility ]:
Reacts with water.
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H314-H350
[ Precautionary Statements ]:
P201-P210-P280-P305 + P351 + P338-P310
[ Hazard Codes ]:
F: Flammable;T: Toxic;
[ Risk Phrases ]:
R45;R11;R34
[ Safety Phrases ]:
53-26-36/37/39-45-16
[ RIDADR ]:
UN 2925
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ HS Code ]:
2931900090
Synthetic Route
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
MedChemComm 4(6) , 932-941, (2013)
The O-tosylsalicylamide S3I-201 (10) was used as a starting point for design and synthesis of novel STAT-3 dimerization inhibitors with improved drug-like qualities. The phosphonic acid 12d and salicy...
Simple and convenient synthesis of tertiary benzanilides using dichlorotriphenylphosphorane. Azumaya I, et al.Tetrahedron 59(13) , 2325-31, (2003)
Cleavage of carboxylic acid esters to acid chlorides with dichlorotriphenylphosphorane. Burton DKJ and Koppes WM.
J. Org. Chem. 40(21) , 3026-3032., (1975)