2-METHOXYFURAN
Names
[ CAS No. ]:
25414-22-6
[ Name ]:
2-METHOXYFURAN
[Synonym ]:
2-Furyl Methyl Ether
Furan,2-methoxy
2-Methoxyfuran
methoxyfuran
2-methoxyfurane
MFCD00003227
2-methoxy-furan
EINECS 246-953-8
Chemical & Physical Properties
[ Density]:
1.065 g/mL at 25 °C(lit.)
[ Boiling Point ]:
110-111°C
[ Molecular Formula ]:
C5H6O2
[ Molecular Weight ]:
98.09990
[ Flash Point ]:
50 °F
[ Exact Mass ]:
98.03680
[ PSA ]:
22.37000
[ LogP ]:
1.28820
[ Vapour Pressure ]:
27.8mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.447(lit.)
[ Storage condition ]:
0-6°C
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Highlyflammable;
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S16-S29-S33
[ RIDADR ]:
UN 1993 3/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2932190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2932190090
[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
J. Org. Chem. 73 , 151-156, (2008)
The early stages of the retro-Diels-Alder reaction are clearly apparent in the structures of the cycloadducts formed between furan or 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methyl...
Asymmetric Friedel-Crafts alkylation of methoxyfuran with nitroalkenes catalyzed by diphenylamine-tethered bis(oxazoline)-Zn(II) complexes.Org. Lett. 9(23) , 4725-8, (2007)
The first catalytic asymmetric Friedel-Crafts reaction of 2-methoxyfuran with nitroalkenes was developed under the catalysis of diphenylamine-tethered bis(oxazoline)-Zn(OTf)2 complexes. The reaction c...
General Acid Catalysis in the Hydrolysis of a Furan Derivative. KANKAANPERA A and AALTONEN R.Acta Chem. Scand. 26(6) , 2537- 2540, (1972)