4-(Dimethylamino)phenylboronic acid

Names

[ Name ]:
4-(Dimethylamino)phenylboronic acid

[Synonym ]:
[4-(dimethylamino)phenyl]boranediol
Boronic acid, B-[4-(dimethylamino)phenyl]-
[4-(Dimethylamino)phenyl]boronic acid
6-Chloro-3-nitro-2-picoline
MFCD04112547
p-Me2N-C6H4-B(OH)2
p-N(CH3)2PhB(OH)2
p-(dimethylamino)phenyboronic acid
(4-(Dimethylamino)phenyl)boronic acid
4-(Dimethylamino)benzeneboronic Acid
4-Me2N(C6H4)B(OH)2
p-dimethylaminophenylboronic acid
4-(N,N-Dimethylamino)phenylboronic acid
4-(Dimethylamino)phenylboronic acid

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
329.9±44.0 °C at 760 mmHg

[ Melting Point ]:
227 °C(lit.)

[ Molecular Formula ]:
C₈H₁₂BNO₂

[ Molecular Weight ]:
164.997

[ Flash Point ]:
153.3±28.4 °C

[ Exact Mass ]:
165.096115

[ PSA ]:
43.70000

[ LogP ]:
1.70

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.547

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis and photophysical investigation of a series of push-pull arylvinyldiazine chromophores.

J. Org. Chem. 8th ed., 77 , 4087-4096, (2012)

A new series of push-pull arylvinyldiazines has been efficiently prepared by aldol condensation between the appropriate methyldiazine and aromatic aldehyde. The optical absorption and emission propert...

Nickel-catalyzed Suzuki-Miyaura reaction of aryl fluorides.

J. Am. Chem. Soc. 48th ed., 133 , 19505-19511, (2011)

Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF(4) and TiF(4), which ena...

Dramatic Effect of the Gelling Cation on the Catalytic Performances of Alginate-Supported Palladium Nanoparticles for the Suzuki-Miyaura Reaction Chtchigrovsky, M.; et al.

Chem. Mater. 8th ed., 24 , 1505-1510, (2012)