1,4-difluoroanthraquinone
Names
[ CAS No. ]:
28736-42-7
[ Name ]:
1,4-difluoroanthraquinone
[Synonym ]:
MFCD00474545
1-fluoroanthracene-9,10-dione derivative
1,4-difluoro-9,10-anthraquinone
1,4-Difluoranthrachinon
1,4-difluoroanthraquinone
1,4-Difluoranthra-9,10-chinon
Chemical & Physical Properties
[ Density]:
1.457g/cm3
[ Boiling Point ]:
401.3ºC at 760 mmHg
[ Melting Point ]:
228-232ºC
[ Molecular Formula ]:
C14H6F2O2
[ Molecular Weight ]:
244.19300
[ Flash Point ]:
152.8ºC
[ Exact Mass ]:
244.03400
[ PSA ]:
34.14000
[ LogP ]:
2.74020
[ Vapour Pressure ]:
1.19E-06mmHg at 25°C
[ Index of Refraction ]:
1.617
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H312-H315-H317-H319-H332-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
R20/21/22;R36/37/38;R43
[ Safety Phrases ]:
S22-S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2914700090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914700090
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
Articles
J. Fluor. Chem. 68(2) , 131-34, (1994)
Heterogeneous organocatalysis for the asymmetric desymmetrization of meso-cyclic anhydrides using silica gel-supported bis-cinchona alkaloids. Kim HS, et al.
Tetrahedron 60(52) , 12051, (2004)
Synthesis of a New Chiral Ligand (QN)2AQN and Its Application to the Catalytic Asymmetric Aminohydroxylation of Methyl Cinnamates. Si-Kun C, et al.
Chin. J. Chem. 25(8) , 982-6, (2005)