Dimethyl chloromalonate

Names

[ Name ]:
Dimethyl chloromalonate

[Synonym ]:
Dimethyl chloromalonate
CHCl(CO2Me)2
2-Chloro-malonic acid dimethyl ester
dimethyl chloropropanedioate
EINECS 249-275-0
dimethyl 2-chloromalonate
Propanedioic acid, 2-chloro-, dimethyl ester
MFCD00042837
2-chlorodimethylmalonate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
215.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₇ClO₄

[ Molecular Weight ]:
166.560

[ Flash Point ]:
106.7±0.0 °C

[ Exact Mass ]:
166.003281

[ PSA ]:
52.60000

[ LogP ]:
0.24

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.431

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Stereoselective synthesis of highly functionalized nitrocyclopropanes via organocatalyic conjugate addition to nitroalkenes.

J. Org. Chem. 71(19) , 7494-7, (2006)

A convenient and novel one-pot organocatalytic methodology for the stereoselective synthesis of highly functionalized nitrocyclopropanes is reported. The addition of dimethyl chloromalonate to a varie...

A preparative method for Synthesis of 4, 5, 6-trichloropyrimidine. Ostrowski S, et al.

ARKIVOC 6 , 905-8, (2000)

New one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes. Yavari I and Baharfar R.

Tetrahedron Lett. 39(9) , 1051-54, (1998)