L-Tryptophanol

Names

[ Name ]:
L-Tryptophanol

[Synonym ]:
(2S)-2-Amino-3-(1H-indol-3-yl)-1-propanol
L-(-)-Tryptophanol
(S)-(-)-2-Amino-3-(3-indolyl)propanol
H-Tryptophanol
2-amino-3-(1H-indol-3-yl)propan-1-ol
1H-Indole-3-propanol, β-amino-, (βS)-
L-Tryptophanol
(2S)-2-amino-3-(1H-indol-3-yl)propan-1-ol
Tryptophanol
MFCD00037970
L-Trp-ol

Chemical & Physical Properties

[ Density]:
1.245g/cm3

[ Boiling Point ]:
444.2ºC at 760mmHg

[ Melting Point ]:
73-77 °C(lit.)

[ Molecular Formula ]:
C₁₁H₁₄N₂O

[ Molecular Weight ]:
190.24200

[ Flash Point ]:
222.5ºC

[ Exact Mass ]:
190.11100

[ PSA ]:
62.04000

[ LogP ]:
1.73030

[ Vapour Pressure ]:
1.13E-08mmHg at 25°C

[ Index of Refraction ]:
-21 ° (C=1, MeOH)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Enantioselective formal synthesis of (+)-dihydrocorynantheine and (-)-dihydrocorynantheol.

J. Org. Chem. 74(3) , 1205-11, (2009)

The enantioselective construction of the 3-ethylindolo[2,3-a]quinolizidine moiety present in numerous indole alkaloids is reported, the key steps being a stereoselective cyclocondensation of (S)-trypt...

Straightforward methodology for the enantioselective synthesis of benzo[a]- and indolo[2,3-a]quinolizidines.

J. Org. Chem. 72(14) , 5193-201, (2007)

An enantioselective two-step route to substituted benzo[a]- and indolo[2,3-a]quinolizidines has been developed. It consists of (i) a stereoselective cyclocondensation of a racemic or prochiral delta-o...

Enantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophylline.

Chem. Commun. (Camb.) 49(19) , 1954-6, (2013)

Starting from (S)-tryptophanol, a formal synthesis of ent-rhynchophylline and ent-isorhynchophylline, involving stereoselective cyclocondensation, spirocyclization, and alkylation reactions, and the f...