dinitramine

Names

[ Name ]:
dinitramine

[Synonym ]:
Caswell No. 335C
EINECS 249-419-2
3-N,3-N-diethyl-2,4-dinitro-6-(trifluoromethyl)benzene-1,3-diamine
Cobex (herbicide)
3-Diethylamino-2,4-dinitro-6-trifluoromethylaniline
2-amino-3,5-dinitro-4-diethylaminobenzotrifluoride
MFCD00144149
Cobeko
N,N-diethyl-2,6-dinitro-4-trifluoromethyl-m-phenylenediamine
N1,N1-diethyl-2,6-dinitro-4-(trifluoromethyl)benzene-1,3-diamine
N1,N1-diethyl-2,6-dinitro-4-trifluoromethyl-m-phenylenediamine
N1,N1-diethyl-2,6-dinitro-4-(trifluoromethyl)-1,3-benzenediamine
Cobexo
Dinitramine [ANSI:BSI:ISO]
USB-3584

Chemical & Physical Properties

[ Density]:
1.465g/cm3

[ Boiling Point ]:
409.1ºC at 760mmHg

[ Melting Point ]:
98-99ºC

[ Molecular Formula ]:
C₁₁H₁₃F₃N₄O₄

[ Molecular Weight ]:
322.24100

[ Flash Point ]:
201.2ºC

[ Exact Mass ]:
322.08900

[ PSA ]:
120.90000

[ LogP ]:
4.57780

[ Index of Refraction ]:
1.474

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS9990000

CHEMICAL NAME :: Toluene-2,4-diamine, N(sup 4),N(sup 4)-diethyl-3,5-dinitro-alpha,alpha,alpha-trifluoro-

CAS REGISTRY NUMBER :: 29091-05-2

LAST UPDATED :: 199612

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C11-H13-F3-N4-O4

MOLECULAR WEIGHT :: 322.28

WISWESSER LINE NOTATION :: FXFFR BZ CNW ENW DN2&2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,80,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C109,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >1200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,302,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,302,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H312-H400

[ Precautionary Statements ]:
P273-P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
R21;R50/53

[ Safety Phrases ]:
S60;S61;S36/S37

[ RIDADR ]:
UN 3077

[ RTECS ]:
XS9990000

[ HS Code ]:
2921519011

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2921519011

[ Summary ]:
2921519011 n1,n1-diethyl-2,6-dinitro-4-(trifluoromethyl)benzene-1,3-diamine。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles

Insights into the formation and degradation mechanisms of methylenedinitramine during the incubation of RDX with anaerobic sludge.

Environ. Sci. Technol. 36(4) , 633-8, (2002)

In an earlier study, we reported that hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) biodegraded with domestic anaerobic sludge to produce a key RDX ring cleavage intermediate that was tentatively iden...

High-performance liquid chromatographic determination of dinitroaniline herbicides in soil and water.

J. Chromatogr. A. 585(1) , 164-7, (1991)

A high-performance liquid chromatographic method for the simultaneous determination of the dinitroaniline herbicides dinitramine, ethalfluralin, trifluralin, pendimethalin and isopropalin in soil and ...

Mechanism of xanthine oxidase catalyzed biotransformation of HMX under anaerobic conditions.

Biochem. Biophys. Res. Commun. 306(2) , 509-15, (2003)

Enzyme catalyzed biotransformation of the energetic chemical octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) is not known. The present study describes a xanthine oxidase (XO) catalyzed biotrans...