Benzoximate

Names

[ Name ]:
Benzoximate

[Synonym ]:
azomate
na-53
Citrastar
EINECS 249-439-1
Benzoic 3-chloro-N-ethoxy-2,6-dimethoxy-benzimidic anhydride
BENZOMATE
MFCD00055458
benzoxamate
ARTABAN
BENZOXIMATE
CITRAZON
3-chloro-α-(EZ)-ethoxyimino-2,6-dimethoxybenzyl benzoate
ACARMATE
ethyl O-benzoyl-3-chloro-2,6-dimethoxybenzohydroximate
Aazomate
benzoic acid anhydride with 3-chloro-N-ethoxy-2,6-dimethoxybenzenecarboximidic acid
benzoic (Ξ)-3-chloro-N-ethoxy-2,6-dimethoxybenzene-1-carboximidic anhydride
NA 53M

Biological Activity

[Description]:

Benzoximate is an acaricide that inhibits fruit tree red spider mite Panonychys ulmi (Koch)[1].

[Related Catalog]:

Research Areas >> Infection

[References]

[1]. Kim YJ, et al. Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). J Econ Entomol. 2006 Jun;99(3):954-8.

Chemical & Physical Properties

[ Density]:
1.21 g/cm3

[ Boiling Point ]:
483.3ºC at 760 mmHg

[ Melting Point ]:
73ºC

[ Molecular Formula ]:
C₁₈H₁₈ClNO₅

[ Molecular Weight ]:
363.79

[ Flash Point ]:
246.1ºC

[ Exact Mass ]:
363.08700

[ PSA ]:
66.35000

[ LogP ]:
3.91230

[ Vapour Pressure ]:
1.7E-09mmHg at 25°C

[ Index of Refraction ]:
1.538

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DF9700000

CHEMICAL NAME :: Benzohydroxamic acid, O-benzoyl-3-chloro-2,6-dimethoxy-N-ethyl-

CAS REGISTRY NUMBER :: 29104-30-1

LAST UPDATED :: 199612

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C18-H18-Cl-N-O5

MOLECULAR WEIGHT :: 363.82

WISWESSER LINE NOTATION :: 1OR BG EO1 FVN2&OVR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15000 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,92,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >15 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (9),41,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (9),41,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 12 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,23,1978

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >15 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (9),41,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4264 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NYKGA7 Noyaku Kagaku. Pesticide Science. (Tokyo, Japan) V.1-3, 1973-76. For publisher information, see NNGADV. Volume(issue)/page/year: 3,123,1976

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
DF9700000

[ HS Code ]:
2918990090

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Determination of benzomate in plant tissues by high-performance liquid chromatography.

J. Chromatogr. A. 257(1) , 151-6, (1983)