3-Chloro-1H-indazole
Names
[ CAS No. ]:
29110-74-5
[ Name ]:
3-Chloro-1H-indazole
[Synonym ]:
EINECS 249-444-9
1H-Indazole,3-chloro
3-Chlor-indazol
3-Chloro-1H-indazole
1H-Indazole, 3-chloro-
3-Chloroindazole
MFCD00067527
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
309.5±15.0 °C at 760 mmHg
[ Melting Point ]:
149 °C (subl.)(lit.)
[ Molecular Formula ]:
C7H5ClN2
[ Molecular Weight ]:
152.581
[ Flash Point ]:
169.9±6.0 °C
[ Exact Mass ]:
152.014130
[ PSA ]:
28.68000
[ LogP ]:
2.71
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.703
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2933990090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933990090
[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
J. Org. Chem. 69 , 5578, (2004)
This paper details the copper-catalyzed N-arylation of pi-excessive nitrogen heterocycles. The coupling of either aryl iodides or aryl bromides with common nitrogen heterocycles (pyrroles, pyrazoles, ...
Metal-mediated coupling of a coordinated isocyanide and indazoles.Dalton Trans. 42(29) , 10394-7, (2013)
A reaction between equimolar amounts of cis-[PdCl2(CNCy)2] (1) and indazole (HInd, 2) or 5-methylindazole (HInd(Me), 3) proceeded in refluxing CHCl3 for ca. 6 h affording the aminocarbene species cis-...