TRIMETHYLSILYLMETHYL ISOCYANIDE

Names

[ CAS No. ]:
30718-17-3

[ Name ]:
TRIMETHYLSILYLMETHYL ISOCYANIDE

[Synonym ]:
MFCD00043056
trimethylsilyl isocyanide
TRIMETHYLSILYLMETHYL ISOCYANIDE

Chemical & Physical Properties

[ Density]:
0.803 g/mL at 25ºC(lit.)

[ Boiling Point ]:
52-53ºC35 mm Hg(lit.)

[ Molecular Formula ]:
C₅H₁₁NSi

[ Molecular Weight ]:
113.23300

[ Flash Point ]:
82 °F

[ Exact Mass ]:
113.06600

[ LogP ]:
1.43210

[ Index of Refraction ]:
n20/D 1.416(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301-H311-H331

[ Precautionary Statements ]:
P210-P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,T

[ Risk Phrases ]:
R11;R23/24/25

[ Safety Phrases ]:
S16;S45;S36/S37/S39

[ RIDADR ]:
UN 1993 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

An improved synthesis of trimethylsilylmethyl isocyanide and some of its reactions with nucleophiles. Smith R and Livinghouse T.

Synth. Commun. 14(7) , 639-646., (1984)

An Improved Synthesis of Trimethylsilylmethyl Isocyanide. Brouwer AC and Van Leusen AM.

Synth. Commun. 16(8) , 865-869., (1986)

A (η¹-iminoacyl) zirconocene complex formed by alkyl isocyanide insertion into the metal-to-carbon bond of (η²-formaldehyde) zirconocene. Erker G, et al.

Organometallics 10(4) , 1201-3, (1991)