1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene

Names

[ Name ]:
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene

[Synonym ]:
MTDA
[(1-Methoxy-2-methylprop-1-en-1-yl)oxy](trimethyl)silane
2-methyl-1-methoxy-1-trimethylsilyloxypropene
1-Propene, 1-methoxy-2-methyl-1-(trimethylsilyloxy)-
methoxy-1-trimethylsilyloxy-2,2-dimethylethylene
1-Methoxy-1-trimethylsilyloxy-2-methyl-1-propene
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
MFCD00010232
1-methoxy-1-trimethylsilyloxy-2-methylpropene
methyl trimethylsilyl dimethylketene acetal
DiMethylketene Methyl TriMethylsilyl Acetal
X1-2231 Fluid
Silane, ((1-methoxy-2-methyl-1-propenyl)oxy)trimethyl-
Silane, [(1-methoxy-2-methyl-1-propen-1-yl)oxy]trimethyl-
[(1-Methoxy-2-methyl-1-propen-1-yl)oxy](trimethyl)silane
1-Methoxy-2-methyl-1-(trimethylsilyloxy)-1-propene
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
137.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₈O₂Si

[ Molecular Weight ]:
174.313

[ Flash Point ]:
14.4±0.0 °C

[ Exact Mass ]:
174.107605

[ PSA ]:
18.46000

[ LogP ]:
3.27

[ Vapour Pressure ]:
8.8±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.419

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 3271 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.

J. Am. Chem. Soc. 129 , 6756, (2007)

Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino ester...

Aldrichimica Acta 17 , 41, (1984)

Polymer J. Tokyo 26 , 169, (1994)