METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE
Names
[ CAS No. ]:
3150-15-0
[ Name ]:
METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE
[Synonym ]:
MFCD00135407
Einecs 221-582-4
METHYL-2,3-ANHYDRO-4,6-O-BENZYLIDENE-A-D-ALLOPYRANOSIDE
methyl-2-3-anhydro-4-6-O-benzylidene*A-D-allopyra
METHYL-2-3-ANHYDRO-4-6-O-BENZYLIDENE*A-D-ALLOPYRANO
Methyl2,3-anhydro-4,6-O-benzylidene-a-D-allopyranose
(1aR,2S,3aR,7aR,7bR)-2-Methoxy-6-phenylhexahydrooxireno[2',3':4,5]pyrano[3,2-d][1,3]dioxine
Biological Activity
[Description]:
[Related Catalog]:
Chemical & Physical Properties
[ Density]:
1.32g/cm3
[ Boiling Point ]:
391ºC at 760mmHg
[ Molecular Formula ]:
C14H16O5
[ Molecular Weight ]:
264.27
[ Flash Point ]:
165.4ºC
[ Exact Mass ]:
264.10000
[ PSA ]:
49.45000
[ LogP ]:
1.23930
[ Index of Refraction ]:
1.577
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ RIDADR ]:
NONH for all modes of transport
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Carbohydr. Res. 238 , 185-92, (1993)
Neighboring-group participation in benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative by diethylaluminum cyanide.
Carbohydr. Res. 338 , 2177-83, (2003)
The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside...
Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane Tóth, G., et al.Carbohydr. Res. 168 , 141-5, (1987)