2-PROPENOIC ACID, 3-BROMO-, ETHYL ESTER, (2Z)-
Names
[ CAS No. ]:
31930-34-4
[ Name ]:
2-PROPENOIC ACID, 3-BROMO-, ETHYL ESTER, (2Z)-
[Synonym ]:
(Z)-3-Bromopropenoic acid ethyl ester
(Z)-ethyl 3-bromopropenate
cis-3-Bromoacrylic Acid Ethyl Ester
(Z)-3-Bromoacrylic acid ethyl ester
(2Z)-3-Bromopropenoic acid ethyl ester
Ethyl cis-3-BroMoacrylate
3-bromo-acrylic acid ethyl ester
ethyl (Z)-3-bromopropenoate
ethyl (Z)-3-bromoacrylate
Ethyl (Z)-3-bromo-2-propenoate
CIS-3-BROMOACRYLIC ACID ETHYL ESTER
(2Z)-3-Bromoacrylic acid ethyl ester
Ethyl (2Z)-3-bromoprop-2-enoate
ethyl 3-bromo-2Z-propenoate
(Z) Ethyl 3-bromoacrylate
Chemical & Physical Properties
[ Density]:
1.475g/cm3
[ Boiling Point ]:
173.7ºC at 760mmHg
[ Molecular Formula ]:
C5H7BrO2
[ Molecular Weight ]:
179.01200
[ Flash Point ]:
58.9ºC
[ Exact Mass ]:
177.96300
[ PSA ]:
26.30000
[ LogP ]:
1.45810
[ Index of Refraction ]:
n20/D 1.481
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;
[ Risk Phrases ]:
36/37/38-52/53-22
[ Safety Phrases ]:
26-36-61
[ RIDADR ]:
UN 3082 9/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ HS Code ]:
2916190090
Synthetic Route
Customs
[ HS Code ]: 2916190090
[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
Articles
Proc. Natl. Acad. Sci. U. S. A. 103(17) , 6665-9, (2006)
3-(2-Deoxy-beta-D-erythro-pentofuranosyl)pyrimido[1,2-alpha]purin-10(3H)-one (M1dG) is a DNA adduct arising from the reaction of 2-deoxyguanosine with the lipid peroxidation product, malondialdehyde, ...
"One-pot" syntheses of malondialdehyde adducts of nucleosides.Nucleosides Nucleotides Nucleic Acids 27(2) , 103-9, (2008)
Short, "one-pot" syntheses of malondialdehyde adducts of deoxyguanosine, deoxyadenosine, and deoxycytidine are described. These syntheses proceed in improved yield and easier purification than previou...
A.B. Smith, S.N. KilényiTetrahedron Lett. 26 , 4419, (1985)