5-Hexen-2-one,5-methyl-

Names

[ Name ]:
5-Hexen-2-one,5-methyl-

[Synonym ]:
5-Methyl-hex-5-en-2-on
5-methyl-hex-5-en-2-one
MFCD00014995
UNII-6OVV4Q22O6
5-Hexen-2-one,5-methyl
5-methyl-6-hexen-2-one
5-Methyl-5-hexen-2-one
EINECS 221-807-6

Chemical & Physical Properties

[ Density]:
0.824g/cm3

[ Boiling Point ]:
147.3ºC at 760mmHg

[ Molecular Formula ]:
C₇H₁₂O

[ Molecular Weight ]:
112.17000

[ Flash Point ]:
38.7ºC

[ Exact Mass ]:
112.08900

[ PSA ]:
17.07000

[ LogP ]:
1.93170

[ Index of Refraction ]:
n20/D 1.431(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H302-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
10-22-41

[ Safety Phrases ]:
26-39

[ RIDADR ]:
UN 1224 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2914190090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914190090

[ Summary ]:
2914190090 other acyclic ketones without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Tetrahedron 41 , 4633, (1985)

Palladium-catalyzed synthesis of allylic tertiary amines from vinylic bromides, olefins, and secondary amines. Patel BA and Heck RF.

J. Org. Chem. 43(20) , 3898-3903, (1978)

Convenient method for the synthesis of lineatin, a pheromone component of Trypodendron lineatum. Baeckstroem P, et al.

J. Org. Chem. 56(10) , 3358-62, (1991)