Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)phosphine]

Names

[ Name ]:
Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)phosphine]

[Synonym ]:
D-valine-t-butyl ester
(R)-valine methyl ester
Val(OtBu)-OH.HCl
R-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane
MFCD03840578
methyl valinate
Valine,methyl ester,L
methyl (R)-valinate
t-butyl D-valinate hydrochloride
L-VALINE METHYL ESTER
(R)-valine t-butyl ester hydrochloride
H-D-Val-OtBu hydrochloride
(R)-XylPhanePhos

Chemical & Physical Properties

[ Boiling Point ]:
785.2ºC at 760 mmHg

[ Melting Point ]:
234-238ºC

[ Molecular Formula ]:
C₄₈H₅₀P₂

[ Molecular Weight ]:
688.85800

[ Flash Point ]:
458.9ºC

[ Exact Mass ]:
688.33900

[ PSA ]:
27.18000

[ LogP ]:
9.55400

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/38

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

Articles

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Org. Lett. 2 , 4173, (2000)

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantiosel...

J. Am. Chem. Soc. 119 , 6207, (1997)