3-methylcrotonoyl chloride

Names

[ Name ]:
3-methylcrotonoyl chloride

[Synonym ]:
3-methyl-but-2-en-1-oyl chloride
3,3-dimethylacrylic acid chloride
EINECS 222-109-4
3-Methyl-2-butenoyl chloride
3-methylcrotonic acid chloride
3,3-Dimethylacryloyl chloride
3,3-Dimethylacrylyl chloride
3,3-dimethylpropenoylchloride
MFCD00000730
3-methylbut-2-enoyl chloride
3-methylcrotonoyl chloride
Senecioyl chloride
2-Butenoyl chloride, 3-methyl-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
146.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₇ClO

[ Molecular Weight ]:
118.562

[ Flash Point ]:
51.1±0.0 °C

[ Exact Mass ]:
118.018539

[ PSA ]:
17.07000

[ LogP ]:
2.13

[ Vapour Pressure ]:
4.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.444

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
reacts

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R10;R14;R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S16

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2916190090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Fumigant toxicity and acetylcholinesterase inhibitory activity of 4 Asteraceae plant essential oils and their constituents against Japanese termite (Reticulitermes speratus Kolbe).

Pestic. Biochem. Physiol. 113 , 55-61, (2014)

This study investigated the fumigant toxicity of 4 Asteraceae plant essential oils and their constituents against the Japanese termite Reticulitermes speratus Kolbe. Fumigant toxicity varied with plan...

Synthesis of potential Rho-kinase inhibitors based on the chemistry of an original heterocycle: 4,4-Dimethyl-3,4-dihydro-1H-quinolin-2-one

Eur. J. Med. Chem. 43(8) , 1730-6, (2008)

A new series of substituted 4,4-dimethyl-3,4-dihydro-1 H-quinolin-2-one have been prepared via condensation of 3,3-dimethylacryloyl chloride with aniline. Details of synthetic procedures are shown. Ou...

Reaction of silylketene acetals with 3, 3-dimethylacryloyl chloride. Rousseau G and Blanco L.

Tetrahedron Lett. 26(35) , 4195-96, (1985)