3-Bromothioanisole

Names

[ Name ]:
3-Bromothioanisole

[Synonym ]:
3-Bromothioanisole
MFCD00041395
1-Bromo-2-(methylsulfanyl)benzene
3-Bromophenyl methyl sulphide
2-(methylthio)bromo benzene
Benzene, 1-bromo-3-(methylthio)-
Benzene, 1-bromo-2-(methylthio)-
3-methylthio-1-bromobenzene
3-Bromophenyl methyl sulfide
1-Bromo-3-(methylsulfanyl)benzene
1-bromo-3-methylsulfanyl-benzene
2-Bromophenyl methyl sulfide
3-bromo thioanisole
1-bromo-3-methylsulphanyl-benzene
1-Bromo-3-(methylthio)benzene
o-Bromo(methylthio)benzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
237.4±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₇BrS

[ Molecular Weight ]:
203.100

[ Flash Point ]:
97.4±22.6 °C

[ Exact Mass ]:
201.945175

[ PSA ]:
25.30000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.624

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Efficient photoacids based upon triarylamine dialkylsulfonium salts. Zhou W, et al.

J. Am. Chem. Soc. 124(9) , 1897-1901, (2002)

Enhancement of acid photogeneration through a para-to-meta substitution strategy in a sulfonium-based alkoxystilbene designed for two-photon polymerization. Xia R, et al.

Chem. Mater. 24(2) , 237-244, (2012)

Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers. Wagner AM and Sanford MS.

J. Org. Chem. 79(5) , 2263-2267, (2014)