3,5-DI-TERT-BUTYL-O-BENZOQUINONE

Names

[ Name ]:
3,5-DI-TERT-BUTYL-O-BENZOQUINONE

[Synonym ]:
3,5-Di-tert-butyl-1,2-benzoquinone
o-Benzoquinone,3,5-di-tert-butyl
o-Benzoquinone, 3,5-di-tert-butyl-
MFCD00001647
3,5-Ditert-butylbenzo-1,2-quinone
3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-
3,5-di-tert-butylbenzo-1,2-quinone
3,5-di-tert-butylcyclohexa-3,5-diene-1,2-dione
EINECS 222-189-0
3,5-DI-TERT-BUTYL-O-BENZOQUINONE
3,5-di-t-butyl-o-benzoquinone
3,5-Bis(2-methyl-2-propanyl)-1,2-benzoquinone

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
302.7±15.0 °C at 760 mmHg

[ Melting Point ]:
112-114 °C(lit.)

[ Molecular Formula ]:
C₁₄H₂₀O₂

[ Molecular Weight ]:
220.307

[ Flash Point ]:
120.6±6.0 °C

[ Exact Mass ]:
220.146332

[ PSA ]:
34.14000

[ LogP ]:
3.04

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.504

[ Stability ]:
Stable. Incompatible with reducing agents, strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914690090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914690090

[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements.

Dalton Trans. 41(48) , 14498-513, (2012)

The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the correspondin...

Versatile chemical transformations of benzoxazole based ligands on complexation with 3d-metal ions.

Inorg. Chem. 51(4) , 2588-96, (2012)

Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DT...

Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.

J. Chromatogr. A. 420(2) , 404-10, (1987)