2-Propynyl chloroformate
Names
[ CAS No. ]:
35718-08-2
[ Name ]:
2-Propynyl chloroformate
[Synonym ]:
propargyloxycarbonyl chloride
2-propynyl chloroformate
MFCD00270127
Carbonochloridic acid, 2-propyn-1-yl ester
chlorocarbonic acid prop-2-ynyl ester
prop-2-yn-1-yl carbonochloridate
2-Propyn-1-yl carbonochloridate
prop-2-ynyl chloroformate
propargylchloroformate
2-Propynyl chloroformate
Chemical & Physical Properties
[ Density]:
1.271±0.06 g/cm
[ Boiling Point ]:
118-122 ºC
[ Molecular Formula ]:
C4H3ClO2
[ Molecular Weight ]:
118.518
[ Flash Point ]:
32.3±16.0 ºC
[ Exact Mass ]:
117.982155
[ PSA ]:
26.30000
[ LogP ]:
1.29
[ Vapour Pressure ]:
23.6±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.450
[ Water Solubility ]:
Sparingly soluble (26 g/L) (25 ºC)
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H302-H311-H314-H331
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T: Toxic;
[ Risk Phrases ]:
10-22-23/24-34
[ Safety Phrases ]:
26-36/37/39-45
[ RIDADR ]:
UN 3390 6.1/PG 1
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
ISRN Org. Chem. 2011 , (2011)
The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0 _C using the extended Grunwald-Winstein ...
Organogold (I) complexes of a C 2-symmetric diacetylide ligand derived from 1, 1'-bi-2-naphthol. Burchell TJ, et al.Inorganica Chim. Acta 359(9) , 2812-2818, (2006)
Synthesis and applications of propargyl pentafluorophenyl carbonate for peptide synthesis. Bhat RG, et al.
Tetrahedron Lett. 43(13) , 2467-2469, (2002)