4-Amino-2,2,6,6-tetramethylpiperidine
Names
[ CAS No. ]:
36768-62-4
[ Name ]:
4-Amino-2,2,6,6-tetramethylpiperidine
[Synonym ]:
4-Piperidinamine, 2,2,6,6-tetramethyl-
2,2,6,6-Tetramethyl-4-aminopiperidine
UNII-ETF220Q65R
2,2,6,6-tetramethylpiperidin-4-amine
4-Amino-2,2,6,6-tetramethylpiperidine
2,2,6,6-tetramethyl-4-piperidylamine
EINECS 253-197-2
Triacetonediamine
MFCD00005984
4-Amino-2,2,6,6-tetramethyl-piperidine
4-Amion-2,2,6,6-Tetramentylniperidine
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
188.5±8.0 °C at 760 mmHg
[ Melting Point ]:
16-18 °C(lit.)
[ Molecular Formula ]:
C9H20N2
[ Molecular Weight ]:
156.268
[ Flash Point ]:
72.2±0.0 °C
[ Exact Mass ]:
156.162643
[ PSA ]:
38.05000
[ LogP ]:
1.60
[ Vapour Pressure ]:
0.6±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.433
[ Water Solubility ]:
soluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TM4290100
- CHEMICAL NAME :
- Piperidine, 4-amino-2,2,6,6-tetramethyl-
- CAS REGISTRY NUMBER :
- 36768-62-4
- BEILSTEIN REFERENCE NO. :
- 0105038
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C9-H20-N2
- MOLECULAR WEIGHT :
- 156.31
- WISWESSER LINE NOTATION :
- T6NTJ B1 B1 DZ F1 F1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 906 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),53,1984
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H290-H302-H314-H412
[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22;R36/37/38
[ Safety Phrases ]:
S26-S36/37-S45-S36/37/39
[ RIDADR ]:
UN 2735 8/PG 3
[ WGK Germany ]:
2
[ RTECS ]:
TM4290100
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
29333999
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933399090
[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Nat. Protoc. 8 , 666, (2013)
We describe the synthesis of the lesser-known stoichiometric oxidation reagent 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1, Bobbitt's salt), as well as of 4-acetamido-...
[Comparative characteristics of the toxicity, safety and nature of the biological effect on the body of 4-hydroxy-2,2,6,6-tetramethylpiperidine and 4-amino-2,2,6,6-tetramethylpiperidine].Gig. Tr. Prof. Zabol. (5) , 53-4, (1984)