2,2,2-trifluoroethyl butyrate
Names
[ CAS No. ]:
371-27-7
[ Name ]:
2,2,2-trifluoroethyl butyrate
[Synonym ]:
MFCD00077609
Butyric Acid 2,2,2-Trifluoroethyl Ester
2,2,2-Trifluoroethyl Butyrate
2,2,2-trifluoroethyl butanoate
Chemical & Physical Properties
[ Density]:
1.127 g/mL at 25 °C(lit.)
[ Boiling Point ]:
113 °C747 mm Hg(lit.)
[ Melting Point ]:
18°C(lit.)
[ Molecular Formula ]:
C6H9F3O2
[ Molecular Weight ]:
170.13000
[ Flash Point ]:
75 °F
[ Exact Mass ]:
170.05500
[ PSA ]:
26.30000
[ LogP ]:
1.89200
[ Index of Refraction ]:
n20/D 1.347(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
UN 3272 3/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
Articles
Acta Chem. Scand. 44(10) , 1032-5, (1990)
Porcine pancreatic lipase-catalysed transesterifications of 2,2,2-trifluoroethyl butyrate with racemic 2-octanol and 1-phenylethanol have been studied in different organic solvents. Solvent hydrophobi...
Asymmetric strecker synthesis of alpha-amino acids via a crystallization-induced asymmetric transformation using (R)-phenylglycine amide as chiral auxiliary.Org. Lett. 3(8) , 1121-4, (2001)
[reaction: see text]. Diastereoselective Strecker reactions based on (R)-phenylglycine amide as chiral auxiliary are reported. The Strecker reaction is accompanied by an in situ crystallization-induce...
Lipase catalysis in the optical resolution of 2-amino-1-phenylethanol derivatives. Kanerva LT, et al.J. Chem. Soc. Perkin Trans. I 14 , 1759-1762., (1992)