Ethyl chloro(difluoro)acetate

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
93.8±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₅ClF₂O₂

[ Molecular Weight ]:
158.531

[ Flash Point ]:
28.9±15.1 °C

[ Exact Mass ]:
157.994614

[ PSA ]:
26.30000

[ LogP ]:
1.64

[ Vapour Pressure ]:
48.8±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.374

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R20/21/22;R34

[ Safety Phrases ]:
S16-S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Pathway for the stereocontrolled Z and E production of alpha,alpha-difluorine-substituted phenyl butenoates.

J. Org. Chem. 71(22) , 8618-21, (2006)

An efficient preparation of pure ethyl Z- and E-alpha,alpha-difluoro-4-phenyl-3-butenoate 1a and 1b together with the corresponding acids 2a and 2b is described. The procedures involve stereocontrolle...

Synthesis of 3-gem-difluoro-2-ethoxy allylic alcohols from ethyl chlorodifluoroacetate. Bégué J-P, et al.

Tetrahedron Lett. 35(3) , 6097-6100, (1994)

A theoretical investigation on the kinetics and reactivity of the gas-phase reactions of ethyl chlorodifluoroacetate with OH radical and Cl atom at 298 K. Mishra BK, et al.

Struct. Chem. 25(2) , 463-470, (2014)

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