Bis(2,2,2-trichloroethyl)Azodicarboxylate

[ Density]:
1.78g/cm3

[ Boiling Point ]:
380.7ºC at 760 mmHg

[ Melting Point ]:
109-111ºC(lit.)

[ Molecular Formula ]:
C₆H₄Cl₆N₂O₄

[ Molecular Weight ]:
380.82500

[ Flash Point ]:
184.1ºC

[ Exact Mass ]:
377.83000

[ PSA ]:
77.32000

[ LogP ]:
4.45220

[ Index of Refraction ]:
1.566

[ Storage condition ]:
2-8°C

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2927000090

Precursor

DownStream

[ HS Code ]: 2927000090

[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Catalytic and enantioselective aza-ene and hetero-Diels-Alder reactions of alkenes and dienes with azodicarboxylates.

Org. Biomol. Chem. 3(12) , 2344-9, (2005)

Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichl...

Stereoselective formation of carbon-carbon bonds via SN2-displacement: synthesis of substituted cycloalkyl[b]indoles.

J. Org. Chem. 70(21) , 8385-94, (2005)

A general asymmetric synthesis of substituted cycloalkyl[b]indoles has been accomplished. The key features of this approach are (1) the utilization of a Japp-Klingemann condensation/Fischer cyclizatio...

A convenient synthesis of N-acetyllactosamine derivatives from lactal.

Carbohydr. Res. 247 , 159-64, (1993)

In a thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal 1 and bis(2,2,2-trichloroethyl) azodicarboxylate (2), the dihydrooxadiazine derivative 3 was obtained in a very high y...

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