Methyl isocyanoacetate

[ Density]:
1.09 g/mL at 25 °C(lit.)

[ Boiling Point ]:
75-76 °C10 mm Hg(lit.)

[ Molecular Formula ]:
C₄H₅NO₂

[ Molecular Weight ]:
99.088

[ Flash Point ]:
193 °F

[ Exact Mass ]:
99.032028

[ PSA ]:
26.30000

[ Index of Refraction ]:
n20/D 1.417(lit.)

[ Storage condition ]:
−20°C

Click to get detail MSDS

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R20/21/22;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2922 8/PG 2

[ WGK Germany ]:
3

[ Hazard Class ]:
8.0， 6.1

[ HS Code ]:
2926909090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Chemoenzymatic construction of a four-component Ugi combinatorial library.

Biotechnol. Bioeng. 69(4) , 457-60, (2000)

The chemoenzymatic preparation of a nine-member Ugi condensation library is described. The carboxylic acid and amine precursors are based on 3-hydroxybutyrate and 4-amino-1-butanol, respectively, and ...

Highly active copper-network catalyst for the direct aldol reaction.

Chem. Asian J. 6(9) , 2545-9, (2011)

The development of a highly active solid-phase catechol-copper network catalyst for direct aldol reaction is described. The catalyst was prepared from an alkyl-chain-linked bis(catechol) and a copper(...

Tetrahedron Lett. 47 , 8641, (2006)

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