n,n'-di-t-butylethylenediamine

Names

[ Name ]:
n,n'-di-t-butylethylenediamine

[Synonym ]:
1,2-Ethanediamine, N,N-bis(1,1-dimethylethyl)-
N,N'-Bis(2-methyl-2-propanyl)-1,2-ethanediamine
N,N'-Di-tert-butylethylenediamine
N,N'-ditert-butylethane-1,2-diamine
N,N'-Di-tert-butyl-ethylenediamine
1,2-Bis(tert-butylamino)ethane
MFCD00014996
n,n'-di-t-butylethylenediamine
N,N'-Di-tert-butylethane-1,2-diamine
N,N′-Di-tert-butylethylenediamine
EINECS 223-769-6

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
208.7±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₂₄N₂

[ Molecular Weight ]:
172.311

[ Flash Point ]:
76.7±11.6 °C

[ Exact Mass ]:
172.193954

[ PSA ]:
24.06000

[ LogP ]:
1.72

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.438

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
KH8587137

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2921290000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921290000

[ Summary ]:
2921290000 other acyclic polyamines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Polymorphism in Lithium Amides: A Structural and Theoretical Study. Synthesis, Mechanism, and NMR Studies of the Lithiation of N,N'-Di-tert-butylethylenediamine.

Inorg. Chem. 35(13) , 4047-4059, (1996)

The lithiation of N,N'-di-tert-butylethylenediamine by MeLi in benzene has been shown by (1)H NMR spectroscopy to proceed via the partially lithiated species [cis-{Li[&mgr;-N(t-Bu)CH(2)CH(2)N(H)t-Bu]}...

Aluminium amides derived from metallation of N,N'-di-tert-butylethylenediamine. Gardiner MG, et al.

J. Chem. Soc., Dalton Trans. 22 , 4163-69, (1996)

New chemistry from the reaction of N, N'-disubstituted ethylenediamines with glyoxal: synthesis of 2-imidazolidinecarboxaldehydes and 1, 4, 6, 9-tetraalkyl-1, 4, 6, 9-tetraaza-5, 10-dioxaperhydroanthracenes. Willer RL, et al.

J. Org. Chem. 50(13) , 2368-72, (1985)