Ethyl (trimethylsilyl)acetate

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
157.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₆O₂Si

[ Molecular Weight ]:
160.286

[ Flash Point ]:
35.0±0.0 °C

[ Exact Mass ]:
160.091949

[ PSA ]:
26.30000

[ LogP ]:
2.26

[ Vapour Pressure ]:
2.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.405

[ Storage condition ]:
Flammables area

Click to get detail MSDS

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Click to get detail synthetic route

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Synthesis of alpha,alpha-dibromo esters as precursors of ynolates.

Chem. Pharm. Bull. 51(4) , 477-78, (2003)

Aliphatic alpha,alpha-dibromo esters, precursors of ynolates, were synthesized via bromination of lithium alpha-bromo ester enolates with 1,2-dibromotetrafluoroethane in good yields. alpha-Trimethylsi...

External chiral ligand-mediated enantioselective Peterson reaction of alpha-trimethylsilanylacetate with substituted cyclohexanones.

Org. Lett. 4 , 4329, (2002)

[reaction: see text] The asymmetric Peterson reaction of an alpha-trimethylsilanylacetate with 4-substituted and 3,5-disubstituted cyclohexanones was mediated by an external chiral tridentate ligand t...

Synth. Commun. 19 , 2441, (1989)

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