2-Bromo-3-nitrotoluene

Names

[ Name ]:
2-Bromo-3-nitrotoluene

[Synonym ]:
2-Bromo-1-methyl-3-nitrobenzene
2-Bromo-3-nitrotoluene
Benzene, 2-bromo-1-methyl-3-nitro-
MFCD00134555
2-brom-1-methyl-3-nitrobenzol

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
282.4±0.0 °C at 760 mmHg

[ Melting Point ]:
38-41 °C(lit.)

[ Molecular Formula ]:
C₇H₆BrNO₂

[ Molecular Weight ]:
216.032

[ Flash Point ]:
104.5±21.8 °C

[ Exact Mass ]:
214.958176

[ PSA ]:
45.82000

[ LogP ]:
2.98

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.593

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

1-Bromo-4-methyl-2-nitro-benzene.

Acta Crystallogr. Sect. E Struct. Rep. Online 67(10) , o2641-o2641., (2011)

In the title compound, C(7)H(6)BrNO(2), the dihedral angle between the nitro group and the phenyl ring is 14.9 (11)°.

Ullmann Synthesis of Six Dimethyldinitrobiphenyls and their Reduction to the Corresponding Diaminodimethylbiphenyls1. Carlin RB and Foltz GE.

J. Am. Chem. Soc. 78(9) , 1997-2000, (1956)

675. Synthesis of fluoranthenes. Part IV. 10-and 11-Substituted fluoranthenes. HorwoodáTucker S.

J. Chem. Soc. , 3213-16, (1949)