TRICHLOROACETIC ANHYDRIDE
Names
[ CAS No. ]:
4124-31-6
[ Name ]:
TRICHLOROACETIC ANHYDRIDE
[Synonym ]:
EINECS 223-925-3
(2,2,2-trichloroacetyl) 2,2,2-trichloroacetate
Perchloroacetic Anhydride
Trichloroacetic anhydride
MFCD00000793
Chemical & Physical Properties
[ Density]:
1.69 g/mL at 25 °C(lit.)
[ Boiling Point ]:
139-141 °C60 mm Hg(lit.)
[ Molecular Formula ]:
C4Cl6O3
[ Molecular Weight ]:
308.75900
[ Flash Point ]:
98-100°C/11mm
[ Exact Mass ]:
305.79800
[ PSA ]:
43.37000
[ LogP ]:
2.79660
[ Index of Refraction ]:
n20/D 1.484(lit.)
[ Stability ]:
Stable. Moisture sensitive - store under dry atmosphere. Incompatible with strong bases, strong oxidizing agents.
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C
[ Risk Phrases ]:
R35
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
J. Pept. Sci. 21 , 630-5, (2015)
The adsorption of proteins at solid-liquid interfaces is important in biosensor and biomaterial applications. Marine mussels affix themselves to surfaces using a highly cross-linked, protein-based adh...
[Anhydride and halogenated-anhydride trihalogenacetic acid interaction with thymidine-5'-phosphate: ways to new activating reagents in nucleotide phosphorylation reactions].Bioorg. Khim. 29(1) , 64-74, (2003)
The interaction of thymidine 5'-phosphate with trichloroacetic anhydride, trichloroacetyl chloride, and tribromoacetyl bromide was studied in dimethylformamide and acetonitrile in the presence of tert...
Analysis of p-chloroamphetamine and a side-chain monofluorinated analogue in rat brain.J. Pharmacol. Methods 25(2) , 147-55, (1991)
p-Chloro-alpha-fluoromethylphenylethylamine (fluoro-p-chloroamphetamine) (FpCA) has been shown in acute studies to be a less potent depletor of the neurotransmitter amine 5-hydroxytryptamine (5-HT) in...