Methyl 2-oxocyclohexanecarboxylate

Names

[ Name ]:
Methyl 2-oxocyclohexanecarboxylate

[Synonym ]:
Cyclohexanecarboxylic acid, 2-oxo-, methyl ester
MFCD00077699
EINECS 255-306-9
Methyl 2-oxocyclohexanecarboxylate
methyl 2-oxocyclohexane-1-carboxylate
2-Oxo-cyclohexanecarboxylic acid methyl ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
230.8±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₂O₃

[ Molecular Weight ]:
156.179

[ Flash Point ]:
94.8±25.4 °C

[ Exact Mass ]:
156.078644

[ PSA ]:
43.37000

[ LogP ]:
0.29

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.464

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2918300090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Highly diastereoselective synthesis of tetrahydrobenzofuran derivatives by palladium-catalyzed reaction of propargylic esters with substituted ß-dicarbonyl compounds. Yoshida M, et al.

Tetrahedron 66(14) , 2675-82, (2010)