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Ethyl 2-butynoate

Names

[ CAS No. ]:
4341-76-8

[ Name ]:
Ethyl 2-butynoate

[Synonym ]:
2-Butynoic acid, ethyl ester
Ethyl Tetrolate
EINECS 224-395-6
MFCD00015182
ethyl but-2-ynoate
Tetrolic Acid Ethyl Ester
Ethyl 2-butynoate
2-Butynoic Acid Ethyl Ester

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
163.0±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H8O2

[ Molecular Weight ]:
112.127

[ Flash Point ]:
53.2±6.7 °C

[ Exact Mass ]:
112.052429

[ PSA ]:
26.30000

[ LogP ]:
1.97

[ Vapour Pressure ]:
2.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.431

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2916190090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Rhodium-catalyzed regio- and stereoselective codimerization of alkenes and electron-deficient internal alkynes leading to 1,3-dienes.

Org. Lett. 10(13) , 2829-31, (2008)

A cationic rhodium(I)/H(8)-BINAP complex catalyzes codimerization of alkenes bearing no alpha-hydrogen and electron-deficient internal alkynes, leading to 1,3-dienes in good yields with moderate to ex...

Phosphine-catalyzed annulation of thioamides and 2-alkynoates: a new synthesis of thiazolines.

J. Org. Chem. 67(13) , 4595-8, (2002)

The annulation of thioamides with 2-alkynoates and 2,3-dienoates under the catalysis of tri-n-butylphosphine was described. The annulation reaction provided a new entry to thiazolines, particularly th...

Increases in microbial nitrogen production and efficiency in vitro with three inhibitors of ruminal methanogenesis.

Can. J. Microbiol. 53(4) , 496-503, (2007)

It was hypothesized that the addition of crotonic acid or 3-butenoic acid would relieve constraints in digestibility observed when methane formation is inhibited by lumazine, propynoic acid, or ethyl ...


More Articles


Related Compounds