Vinylboronic anhydride pyridine complex
Names
Chemical & Physical Properties
[ Boiling Point ]:
78-80 ℃
[ Melting Point ]:
49 - 53 ℃
[ Molecular Formula ]:
C11H14B3NO3
[ Molecular Weight ]:
240.66700
[ Flash Point ]:
80 ℃ - 闭杯
[ Exact Mass ]:
241.12500
[ PSA ]:
40.58000
[ LogP ]:
1.77160
[ Storage condition ]:
-20 °C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H319
[ Precautionary Statements ]:
P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 6th ed., 7 , 1161-1164, (2005)
[reaction: see text] Straightforward methods for palladium-catalyzed alkenylation of aziridines with alkenyl halides and copper-catalyzed alkenylation of aziridines with alkenyl boronic acids have bee...
Stereoselective isomerisation of N-allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis.Chemistry 3rd ed., 14 , 886-894, (2008)
In the presence of rhodium(I) hydride catalysts, tertiary N-allylamines are known to isomerise into E enamines. In contrast, we have recently found that N-allylaziridines isomerise to form Z enamines....
The alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent for improved selectivity to the cytosine base in RNABioorg. Med. Chem. 8th ed., 18 , 2894-2901, (2010)
The ethylene-connected 2-amino-6-vinylpurine (AVP) crosslinking agent exhibited improved reactivity and selectivity to the cytosine base in RNA.