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(2R)-2-Methoxy-3,4-dihydro-2H-pyran

Names

[ CAS No. ]:
4454-05-1

[ Name ]:
(2R)-2-Methoxy-3,4-dihydro-2H-pyran

[Synonym ]:
2-Methoxy-3,4-dihydro-2H-pyran
3,4-Dihydro-2-Methoxy-2H-pyran
MFCD00006560
(2R)-2-Methoxy-3,4-dihydro-2H-pyran
2H-Pyran, 3,4-dihydro-2-methoxy-, (2R)-
EINECS 224-698-3

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
149.3±39.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H10O2

[ Molecular Weight ]:
114.142

[ Flash Point ]:
16.7±0.0 °C

[ Exact Mass ]:
114.068077

[ PSA ]:
18.46000

[ LogP ]:
-0.09

[ Vapour Pressure ]:
5.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.451

[ Storage condition ]:
Flammables area

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UP7900000
CHEMICAL NAME :
2H-Pyran, 3,4-dihydro-2-methoxy-
CAS REGISTRY NUMBER :
4454-05-1
BEILSTEIN REFERENCE NO. :
0107274
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C6-H10-O2
MOLECULAR WEIGHT :
114.16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 30,545,1988
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 30,545,1988 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1410 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - other changes
REFERENCE :
VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 30,545,1988
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8044 ppm/1H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - pleural effusion
REFERENCE :
VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 30,545,1988
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
4920 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - dyspnea Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
VHTODE Veterinary and Human Toxicology. (American College of Veterinary and Comparative Toxicology, Publication Office, Comparative Toxicology, Manhattan, KS 66506) V.19- 1977- Volume(issue)/page/year: 30,545,1988

Safety Information

[ Hazard Codes ]:
F:Highlyflammable;Xn:Harmful;

[ Risk Phrases ]:
R11;R22

[ Safety Phrases ]:
S9-S33-S16-S36-S26

[ RIDADR ]:
1993

[ RTECS ]:
UP7900000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%


Related Compounds