3′-Fluoro-4′-methoxyacetophenone

Names

[ CAS No. ]:
455-91-4

[ Name ]:
3′-Fluoro-4′-methoxyacetophenone

[Synonym ]:
Ethanone, 1-(3-fluoro-4-methoxyphenyl)-
MFCD00026219
1-(3-Fluoro-4-methoxyphenyl)-1-ethanone
3'-Fluoro-4'-methoxyacetophenone
3′-Fluoro-4′-methoxyacetophenone
1-(3-Fluoro-4-methoxyphenyl)ethanone
1-(3-fluoro-4-methoxyphenyl)ethan-1-one
EINECS 207-253-8
1VR CF DO1

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
262.9±20.0 °C at 760 mmHg

[ Melting Point ]:
92-94 °C(lit.)

[ Molecular Formula ]:
C₉H₉FO₂

[ Molecular Weight ]:
168.165

[ Flash Point ]:
109.4±16.7 °C

[ Exact Mass ]:
168.058655

[ PSA ]:
26.30000

[ LogP ]:
1.79

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.488

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of some Fluorine-Containing Analogs and Derivatives of Medicinals. Minor JT and Vanderwerf CA.

J. Org. Chem. 17(11) , 1425-30, (1952)