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((trifluoromethyl)thio)benzene

Names

[ CAS No. ]:
456-56-4

[ Name ]:
((trifluoromethyl)thio)benzene

[Synonym ]:
MFCD00040839
(Trifluoromethylthio)Benzene
trifluoromethylsulfanylbenzene
Sulfide phenyl trifluoromethyl
Benzene, [(trifluoromethyl)thio]-
Trifluoromethyl phenyl thioether [(Trifluoromethyl)thio]benzene
[(Trifluoromethyl)sulfanyl]benzene
Phenyl trifluoromethyl sulfide
EINECS 207-270-0
α,α,α-Trifluorothioanisole
((trifluoromethyl)thio)benzene

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
106.2±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H5F3S

[ Molecular Weight ]:
178.175

[ Flash Point ]:
18.0±27.3 °C

[ Exact Mass ]:
178.006409

[ PSA ]:
25.30000

[ LogP ]:
3.57

[ Vapour Pressure ]:
33.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.494

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16-S36-S36/37/39-S23

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2930909090

Precursor & DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

J. Org. Chem. 11th ed., 68 , 4457-4463, (2003)

A new and efficient method for the preparation of tri- and difluoromethylsilanes using magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes is reported using tri- and diflu...

Synthesis of sulfoxides by the hydrogen peroxide induced oxidation of sulfides catalyzed by iron tetrakis(pentafluorophenyl)porphyrin: scope and chemoselectivity.

J. Org. Chem. 10th ed., 69 , 3586-3589, (2004)

The oxidation of sulfides with H(2)O(2) catalyzed by iron tetrakis(pentafluorophenyl)porphyrin in EtOH is an efficient and chemoselective process. With a catalyst concentration 0.03-0.09% of that of t...

Synthesis and structure-activity relationships of benzophenone hydrazone derivatives with insecticidal activity.

Pest Manag. Sci. 2nd ed., 57 , 191-202, (2001)

A broad range of benzophenone hydrazone derivatives was prepared and tested against selected chewing insect pests, allowing the analysis of structure-activity relationships. Good activity was found on...


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Related Compounds