CHLORODICARBONYL[1-(I-PROPYLAMINO)-2,3,4,5-TETRAPHENYLCYCLOPENTADIENYL]RUTHENIUM(II)

Names

[ Name ]:
CHLORODICARBONYL[1-(I-PROPYLAMINO)-2,3,4,5-TETRAPHENYLCYCLOPENTADIENYL]RUTHENIUM(II)

[Synonym ]:
Chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II)
Chlorodicarbonyl[1-(i-propylamino)-2,3,4,5-tetraphenylcyclopentadienyl]ruthenium(II)

Chemical & Physical Properties

[ Melting Point ]:
197ºC (DEC.)

[ Molecular Formula ]:
C₃₄H₂₈ClNO₂Ru

[ Molecular Weight ]:
619.11500

[ Exact Mass ]:
619.08500

[ PSA ]:
12.03000

[ LogP ]:
6.68720

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26;S36/S37

[ RIDADR ]:
NONH for all modes of transport

Articles

(S)-selective dynamic kinetic resolution of secondary alcohols by the combination of subtilisin and an aminocyclopentadienylruthenium complex as the catalysts.

J. Am. Chem. Soc. 125 , 11494, (2003)

A new procedure for the dynamic kinetic resolution (DKR) of racemic alcohols into single enantiomers is described. This procedure employs surfactant-treated subtilisin as an (S)-selective resolving ca...