Methyl 3-phenyl-2-propynoate
Names
[ CAS No. ]:
4891-38-7
[ Name ]:
Methyl 3-phenyl-2-propynoate
[Synonym ]:
Phenylpropynoic acid methyl ester
Methyl Phenylpropiolate
Propiolic acid, 3-phenyl-, methyl ester
methyl 3-phenylprop-2-ynoate
Phenylpropargylic Acid Methyl Ester
2-Propynoic acid, 3-phenyl-, methyl ester
Methyl 3-phenyl-2-propynoate
MFCD00041685
Phenylpropiolic Acid Methyl Ester
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
247.9±9.0 °C at 760 mmHg
[ Melting Point ]:
26ºC
[ Molecular Formula ]:
C10H8O2
[ Molecular Weight ]:
160.169
[ Flash Point ]:
117.4±6.7 °C
[ Exact Mass ]:
160.052429
[ PSA ]:
26.30000
[ LogP ]:
3.19
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.546
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319
[ Precautionary Statements ]:
P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2916399090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916399090
[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
J. Am. Chem. Soc. 127(36) , 12466-7, (2005)
Transition metal-catalyzed [m+n+o] carbocyclization reactions provide powerful methods for the construction of complex polycyclic systems that are generally not accessible through classical pericyclic...
Steric effects on reactivity in silicon chemistry. Cartledge FK.Organometallics 2(3) , 425-430, (1983)
Preparation and Structures of Methyl Phenylpropiolate-Iron Carbonyl Complexes. A New Dicarbonyl-p-cyclopentadienyloxy-s-vinyliron Compound. Dahl LF, et al.
J. Am. Chem. Soc. 88(3) , 446-452, (1966)