(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

Names

[ Name ]:
(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

[Synonym ]:
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N-methyl-N-(phenylmethyl)-
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a
MFCD04117686
N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
3,4-a′]dinaphthalen-4-yl)methylamine

Chemical & Physical Properties

[ Boiling Point ]:
635.4±48.0 °C at 760 mmHg

[ Melting Point ]:
155-159ºC

[ Molecular Formula ]:
C₂₈H₂₂NO₂P

[ Molecular Weight ]:
435.453

[ Flash Point ]:
338.1±29.6 °C

[ Exact Mass ]:
435.138824

[ PSA ]:
29.52000

[ LogP ]:
7.91

[ Vapour Pressure ]:
0.0±1.9 mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2921499090

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Highly enantioselective rhodium-catalyzed hydrogenation of beta-dehydroamino acid derivatives using monodentate phosphoramidites.

J. Am. Chem. Soc. 124 , 14552, (2002)

New and very easily accessible monodentate phosphoramidite ligands have been developed that lead to excellent ee's and full conversions in the hydrogenation of (E)- and (Z)-beta-dehydroamino acid deri...

J. Organomet. Chem. 692 , 428, (2007)