Phenylsulfonylacetone

Names

[ CAS No. ]:
5000-44-2

[ Name ]:
Phenylsulfonylacetone

[Synonym ]:
1-(benzenesulfonyl)propan-2-one
Phenylsulfonylacetone
MFCD00047794

Chemical & Physical Properties

[ Density]:
1.228 g/cm3

[ Boiling Point ]:
371.7ºC at 760 mmHg

[ Melting Point ]:
55-59 °C(lit.)

[ Molecular Formula ]:
C₉H₁₀O₃S

[ Molecular Weight ]:
198.23900

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
198.03500

[ PSA ]:
59.59000

[ LogP ]:
2.13010

[ Index of Refraction ]:
1.526

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Comparative Asymmetric Reduction of Phenylthioacetone,(±)-Phenylsulfinylacetone and Phenylsulfonylacetone with Fermenting Bakers’ Yeast Iriuchijima S and Kojima N.

Agric. Biol. Chem. 42.2 , 451-455, (1978)

Arylation of enolate anions with (. eta. 6-chlorobenzene)(. eta. 5-cyclopentadienyl) iron (II) hexafluorophosphate Moriarty RM and Gill US

Organometallics 5.2 , 253-256, (1986)

Copper-Catalyzed Coupling Cyclization of gem-Difluoroalkenes with Activated Methylene Carbonyl Compounds: Facile Domino Access to Polysubstituted Furans Zhang, Xuxue, et al.

Org. Lett. 17.11 , 2708-2711, (2015)