diethylmalonic acid
Names
[ CAS No. ]:
510-20-3
[ Name ]:
diethylmalonic acid
[Synonym ]:
T0517-6168
diethyl-propanedioic acid
Diethyl malonic acid
3,3-Pentanedicarboxylic acid
Malonic acid,diethyl
Propanedioic acid,diethyl
Diaethyl-malonsaeure
2,2-Diethylmalonic acid
EINECS 208-111-8
MFCD00004202
Chemical & Physical Properties
[ Density]:
1.2g/cm3
[ Boiling Point ]:
323.8ºC at 760mmHg
[ Melting Point ]:
129-131ºC(lit.)
[ Molecular Formula ]:
C7H12O4
[ Molecular Weight ]:
160.16800
[ Flash Point ]:
163.9ºC
[ Exact Mass ]:
160.07400
[ PSA ]:
74.60000
[ LogP ]:
0.96200
[ Index of Refraction ]:
1.475
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2917190090
Synthetic Route
Customs
[ HS Code ]: 2917190090
[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Prep. Biochem. 11(3) , 339-50, (1981)
This paper describes the complete chemical synthesis of 4-methylene-DL-glutamic acid from diethylmalonate, formaldehyde and diethyl acetamidomalonate. The amino acid was obtained pure following ion-ex...
Evaluation of malonanilides as new stabilizers for double-base propellants.J. Hazard. Mater. 73(3) , 237-44, (2000)
Five malonanilide derivatives (M1-M5) were prepared by the reaction of ethyl malonate with aniline derivatives. These compounds were investigated as new stabilizers for double-base propellants (DBPs)....
A general and mild copper-catalyzed arylation of diethyl malonate.Org. Lett. 4(2) , 269-72, (2002)
[reaction: see text] A general method for the synthesis of alpha-aryl malonates is described. The coupling of an aryl iodide and diethyl malonate in the presence of Cs(2)CO(3) and catalytic amounts of...