2-(methylthio)cyclohexanone

Names

[ Name ]:
2-(methylthio)cyclohexanone

[Synonym ]:
2-methylsulfanyl-cyclohexanone
2-(Methylthio)cyclohexanone
MFCD00209603
2-methylthiocyclohexane
2-Methylmercapto-cyclohexanon

Chemical & Physical Properties

[ Density]:
1.069 g/mL at 25ºC(lit.)

[ Boiling Point ]:
45ºC10.1 mm Hg(lit.)

[ Molecular Formula ]:
C₇H₁₂OS

[ Molecular Weight ]:
144.23500

[ Flash Point ]:
193 °F

[ Exact Mass ]:
144.06100

[ PSA ]:
42.37000

[ LogP ]:
1.86110

[ Index of Refraction ]:
n20/D 1.508(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Studies on the stereoselectivity of hydride reductions on 2-(methylthio)-and 2-(methylsulfonyl) cyclohexanones. Carmen CM, et al.

J. Org. Chem. 52(16) , 3619-3625, (1987)

Nitrone formation in phosphate buffer and aqueous solutions: novel chemistry inspired by a natural product. Pansanit A, et al.

Tetrahedron Lett. 53(16) , 2129-2131, (2012)

Axial/equatorial proportions for 2-substituted cyclohexanones. Basso EA, et al.

J. Org. Chem. 58(27) , 7865-7869, (1993)