Pyridinium trifluoromethanesulfonate
Names
[ CAS No. ]:
52193-54-1
[ Name ]:
Pyridinium trifluoromethanesulfonate
[Synonym ]:
MFCD00274656
pyridine*HOTf
methanesulfonic acid, 1,1,1-trifluoro-, compd. with pyridine (1:1)
Pyridinium trifluoromethanesulfonate
Pyridinium Triflate
pyridinium trifluoromethylsulfonate
Chemical & Physical Properties
[ Boiling Point ]:
162ºC at 760 mmHg
[ Melting Point ]:
221-223ºC(lit.)
[ Molecular Formula ]:
C6H6F3NO3S
[ Molecular Weight ]:
229.177
[ Flash Point ]:
129.1ºC
[ Exact Mass ]:
229.002045
[ PSA ]:
75.64000
[ LogP ]:
2.55640
[ Appearance of Characters ]:
Powder | white
[ Water Solubility ]:
It is miscible with water, soluble in polar solvents.
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
20/21/22-36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2933399090
Customs
[ HS Code ]: 2933399090
[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 148 , 203-214, (2015)
Infrared spectroscopy (4000-400 cm(-1)) in the wide temperature range, from 11 to 473 K, has been used to investigate the non-centrosymmetric pyridinium trifluoromethanesulfonate crystal, exhibiting s...
Brønsted acid catalyzed α'-functionalization of silylenol ethers with indoles.Angew. Chem. Int. Ed. Engl. 54(15) , 4641-5, (2015)
A new method which enables carbon-carbon bond formation at the α'-position of silylenol ethers by using catalytic amounts of pyridinium triflate is reported. This chemistry successfully produces, stru...
Effect of Lewis and Brønsted acids on the homopolymerization of acrylates and their copolymerization with 1-alkenes. Luo R, et al.J. Polym. Sci. A Polym. Chem. 46(16) , 5499-5505, (2008)