2-Methyl-2-propanyl bromoacetate

Names

[ Name ]:
2-Methyl-2-propanyl bromoacetate

[Synonym ]:
Bromoacetic Acid tert-Butyl Ester
E1VOX1&1&1
2-Methyl-2-propanyl bromoacetate
tert-butyl 2-bromoacetate
tert-Butyl Bromoacetate
EINECS 226-133-6
Acetic acid, 2-bromo-, 1,1-dimethylethyl ester
Acetic acid, bromo-, 1,1-dimethylethyl ester
MFCD00000188
T-BUTYL 2-BROMOACETATE

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
164.0±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₁BrO₂

[ Molecular Weight ]:
195.054

[ Flash Point ]:
49.4±0.0 °C

[ Exact Mass ]:
193.994232

[ PSA ]:
26.30000

[ LogP ]:
2.07

[ Vapour Pressure ]:
2.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.457

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S24/25-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2915709000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Gas chromatography with parallel hard and soft ionization mass spectrometry.

Rapid Commun. Mass Spectrom. 29(1) , 91-9, (2014)

Mass spectrometric identification of compounds in chromatography can be obtained from molecular masses from soft ionization mass spectrometry techniques such as field ionization (FI) and fragmentation...

Preoperative Detection and Intraoperative Visualization of Brain Tumors for More Precise Surgery: A New Dual-Modality MRI and NIR Nanoprobe.

Small 11 , 4517-25, (2015)

In clinical practice, it is difficult to identify tumor margins during brain surgery due to its inherent infiltrative character. Herein, a unique dual-modality nanoprobe (Gd-DOTA-Ag2S QDs, referred as...

Synthesis of fused heteroarylprolines and pyrrolopyrroles.

J. Org. Chem. 69 , 4656-4662, (2004)

Fused heteroarylprolines were prepared starting from 4-oxo-N-(PhF)proline benzyl ester (6, PhF = 9-(9-phenylfluorenyl)) following two approaches. First, allylation of oxoproline 6 followed by Wacker o...