3'-Methylacetanilide

Names

[ CAS No. ]:
537-92-8

[ Name ]:
3'-Methylacetanilide

[Synonym ]:
N-Acetyl-m-toluidine
N-(3-methylphenyl)acetamide
m-Acetotoluidide
m-Acetotoluidine
MFCD00014962
EINECS 208-678-1

Chemical & Physical Properties

[ Density]:
1.52g/cm3

[ Boiling Point ]:
303 °C(lit.)

[ Melting Point ]:
65-67 °C(lit.)

[ Molecular Formula ]:
C₉H₁₁NO

[ Molecular Weight ]:
149.19000

[ Flash Point ]:
222.1ºC

[ Exact Mass ]:
149.08400

[ PSA ]:
29.10000

[ LogP ]:
2.02640

[ Vapour Pressure ]:
16 mm Hg ( 163 °C)

[ Index of Refraction ]:
1.567

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AN2875000

CHEMICAL NAME :: m-Acetotoluidide

CAS REGISTRY NUMBER :: 537-92-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C9-H11-N-O

MOLECULAR WEIGHT :: 149.21

WISWESSER LINE NOTATION :: 1VMR C1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1450 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,20,1971

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AN2875000

[ HS Code ]:
2924299090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

3'-Methylacetanilide and N-benzylthioacetamide at low temperature.

Acta Crystallogr. C 64(Pt 11) , o599-603, (2008)

Molecules of the title compounds, 3'-methylacetanilide [or N-(m-tolyl)acetamide], C(9)H(11)NO, (I), and N-benzylthioacetamide, C(9)H(11)NS, (II), are connected by a framework of intermolecular N-H...O...