Methyl 2-bromopropionate

Names

[ Name ]:
Methyl 2-bromopropionate

[Synonym ]:
Methyl2-bromopropionate
2-Bromopropionic
methyl DL-2-bromo-propionate
2-BROMOPROPIONATE
methyl2-bromopropanoate
Methyl 2-bromopropanoate
methyl 2-bromoacrylate
EINECS 226-642-3
Methyl α-bromopropionate
Propanoic acid, 2-bromo-, methyl ester
DL-2-Methyl broMopropionic
Methyl 2-bromopropionate
DL-a-bromopropionate
MFCD00000143
2-bromopropionic acid-methyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
145.9±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₇BrO₂

[ Molecular Weight ]:
167.001

[ Flash Point ]:
51.7±0.0 °C

[ Exact Mass ]:
165.962936

[ PSA ]:
26.30000

[ LogP ]:
1.19

[ Vapour Pressure ]:
4.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.451

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
Immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S26-S27-S36/37/39-S45-S37/39

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Design and synthesis of digitally encoded polymers that can be decoded and erased.

Nat. Commun. 6 , 7237, (2015)

Biopolymers such as DNA store information in their chains using controlled sequences of monomers. Here we describe a non-natural information-containing macromolecule that can store and retrieve digita...

The first proton sponge-based amino acids: synthesis, acid-base properties and some reactivity.

Org. Biomol. Chem. 13 , 8524-32, (2015)

The first hybrid base constructed from 1,8-bis(dimethylamino)naphthalene (proton sponge or DMAN) and glycine, N-methyl-N-(8-dimethylamino-1-naphthyl)aminoacetic acid, was synthesised in high yield and...

Synthesis of hollow mesoporous silica nanoparticles with tunable shell thickness and pore size using amphiphilic block copolymers as core templates.

Dalton Trans. 43(31) , 11834-42, (2014)

This paper presents a facile method for the fabrication of uniform hollow mesoporous silica nanoparticles (HMSNs) with tunable shell thickness and pore size. In this method, a series of amphiphilic bl...