Methyl 4-methoxysalicylate

Names

[ CAS No. ]:
5446-02-6

[ Name ]:
Methyl 4-methoxysalicylate

[Synonym ]:
methyl 2-hydroxy-4-methoxybenzoate
MFCD00008424
EINECS 226-657-5

Chemical & Physical Properties

[ Density]:
1.216g/cm3

[ Boiling Point ]:
134°C 7mm

[ Melting Point ]:
50-53 °C(lit.)

[ Molecular Formula ]:
C₉H₁₀O₄

[ Molecular Weight ]:
182.17300

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
182.05800

[ PSA ]:
55.76000

[ LogP ]:
1.18740

[ Index of Refraction ]:
1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The first asymmetric total synthesis of (+)-coriandrone A and B.

Org. Biomol. Chem. 11(39) , 6686-90, (2013)

The first enantioselective total synthesis of (+)-coriandrone A and B, two bioactive natural products, has been achieved in 10 steps and 11 steps starting from commercially available methyl 2-hydroxy-...