(R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane

Names

[ Name ]:
(R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane

[Synonym ]:
1,3-Dioxolane, 4-(chloromethyl)-2,2-dimethyl-
(r)-(+)-4-chloromethyl-2,2-dimethyl-1,3-dioxolane
4-(CHLOROMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
(4R)-4-(chloromethyl)-2,2-dimethyl-1,3-dioxolane
1,3-DIOXOLANE, 4-CHLOROMETHYL-2,2-DIMETHYL-
MFCD00273371
1,3-Dioxolane, 4-(chloromethyl)-2,2-dimethyl-, (4R)-
UNII:0366925SM9
(R)-(+)-4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
156.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₁ClO₂

[ Molecular Weight ]:
150.603

[ Flash Point ]:
54.5±18.4 °C

[ Exact Mass ]:
150.044754

[ PSA ]:
18.46000

[ LogP ]:
0.83

[ Vapour Pressure ]:
3.8±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.421

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R41

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 1993

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2932999099

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine.

Tetrahedron Asymmetry 6 , 1283, (1995)

This communication discloses the first instance of the enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine. The methodology relies on Beak's sparteine-mediated, enantioselective deproto...