Ethyl 4-bromobenzoate

Names

[ Name ]:
Ethyl 4-bromobenzoate

[Synonym ]:
Benzoic acid,p-bromo-,ethyl ester
4-bromoethyl benzoate
p-(Ethoxycarbonyl)phenyl bromide
Benzoic acid, p-bromo-, ethyl ester (8CI)
Ethyl-4-bromobenzoate
p-bromobenzoic acid ethyl ester
EINECS 227-347-2
MFCD00016329
4-Br-C6H4CO2Et
Ethyl 4-bromobenzoate
4-bromo-benzoic acid ethyl ester
Benzoic acid, 4-bromo-, ethyl ester
4-Br-C6H4COOEt
ETHYL P-BROMOBENZOATE
Benzoic acid,4-bromo-,ethyl ester
Benzoic acid, p-bromo-, ethyl ester

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
255.5±0.0 °C at 760 mmHg

[ Melting Point ]:
18 °C

[ Molecular Formula ]:
C₉H₉BrO₂

[ Molecular Weight ]:
229.071

[ Flash Point ]:
121.9±19.8 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
3.48

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.542

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
UN 3082 9 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Cross-couplings between benzylic and aryl halides "on water": synthesis of diarylmethanes.

Chem. Commun. (Camb.) 46(4) , 562-4, (2010)

A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide...

Chemoselective Reduction of Esters to Aldehydes by Potassium Diisobutyl-t-butoxyaluminum Hydride (PDBBA). Chae MJ, et al.

Bull. Korean Chem. Soc. 28(12) , 2517, (2007)